METAL SOLUTIONS

EOS StainlessSteel 17-4PH

Material Data Sheet

EOS StainlessSteel 17-4PH

EOS StainlessSteel 17-4PH is a martensitic precipitation hardening stainless steel with high strenght and toughness. EOS 17-4PH corresponds to ASTM A564 (UNS17400, 17-4PH). 17-4PH can be heat treated for use in components with different requirements. It can be widely used in engineering solutions and in components in the medical field.

MAIN CHARACTERISTICS

  • High strength
  • Good corrosion resistance

TYPICAL APPLICATIONS

  • Surgical tools
  • Pump components
  • Paper mill equipment

The EOS Quality Triangle

EOS uses an approach that is unique in the AM industry, taking each of the three central technical elements of the production process into account: the system, the material and the process. The data resulting from each combination is assigned a Technology Readiness Level (TRL) which makes the expected performance and production capability of the solution transparent.

EOS incorporates these TRLs into the following two categories:
 
  • Premium products (TRL 7-9): offer highly validated data, proven capability and reproducible part properties. 
  • Core products (TRL 3 and 5): enable early customer access to newest technology still under development and are therefore less mature with less data.

All of the data stated in this material data sheet is produced according to EOS Quality Management System and international standards
EOS 3D Printing Solutions Quality Triangle

POWDER PROPERTIES

The chemical composition of EOS stainlessSteel 17-4PH is in compliance with ASTM A564.

Powder Chemical Composition (wt.-%)

Element Min. Max.
Cr 15 17.5
Ni 3 5
Cu 3 5
Si 0 1
Mn 0 1
C 0 0.07
P 0 0.04
S 0 0.03
Nb + Ta 0.15 0.45

Powder Particle Size

GENERIC PARTICLE SIZE DISTRIBUTION 15 - 65 μm

HEAT TREATMENT

Description

EOS 17-4PH can be heat treated to match various needs of different applications. The two step heat treatment can be performed under vacuum or inert gas atmosphere. First step is solution annealing to minimize amount of austenite in the martensitic matrix. The needed hardness and strength is achieved through aging treatment where hardening takes place through forming of precipitates.

Steps

Solution annealing: 
0.5-1 h at 1040 °C (±15 °C) measured from the part followed by rapid air cooling to room temperature (below 32 °C). Cooling rate 5-60 °C/min. Reaching room temperature before starting aging treatment is required to achieve desired microstructure.

Ageing: 
Peak hardness of 42 HRC Is achieved with H900 ageing treatment of 1 h at 480 °C (±10 °C) measured from the part followed by air cooling. Mechanical properties presented in this document achieved through this aging procedure. For lower hardness and strength choose aging procedure according to the table.

Condition Ageing temperature [°C] Hold time [h] Cooling Hardness [HRC]
H900 480 1 Air 42
H925 495 4 Air 38
H1025 550 4 Air 36
H1075 580 4 Air 34
H1100 595 4 Air 32
H1150 620 4 Air 28

 

CYTOTOXICITY

Cytotoxicity tests were done according to ISO 10993-5. It included growth inhibition tests evaluated from two endpoints (XTT & BCA).
Tests were done with as-manufactured cubes. EOS StainlessSteel 17-4PH cubes were extracted under agitation for 24±2h with DMEM 10% FBS. L929 cells were then incubated for 68 – 72h with the following concentrations of the test extract: 13.2%, 19.8%, 29.6%, 44.4%, 66.7% and 100%. Surface/volume ratio used was 3cm2/mL.

In this study under the given conditions no leachable substances were released in cytotoxic concentrations from the test item as confirmed by two different endpoints (XTT, BCA).

Process Data Sheet

EOS StainlessSteel 17-4PH for EOS M 290 | 40/80 µm

EOS M 290 - 40 µm - TRL 3

Process Information Metal

This process product is optimized for flexible and fast production of 17-4PH parts with EOS M 290 system. The parameter  set has three different layer thickness options that can all be utilized within the same build: 40µm, 80 µm and 40/80 µm Skin. For high productivity needs a 80 µm parameter set is included with a build rate more than double the long established 40 µm parameter set. Both can be used separately for different parts or combined by using 40/80 µm Skin with faster 80 µm for the core of the part and higher quality 40 µm building for the surface of the part with defined thickness. Sectionioning parts in vertical direction for different parameters is also possible.

System Setup EOS M 290
EOS Material set 17-4PH_040_080_Core M291
Required Software Plan EOS BUILD
Software Requirements

EOSPRINT 2.14 or newer
EOSYSTEM 2.18 or newer

Recoater Blade Ceramic
Nozzle EOS Grid Nozzle
Inert gas Argon
Sieve 75 µm
Additional Information
Layer Thickness 40/80 µm
Volume Rate 4.1-7.9 mm³/s
Typical Dimensional Change after HT [%] +0.2 %

Chemical and Physical Properties of Parts

Etched micrograph of powder

Microstructure of the Produced Parts

Defects Thickness Result Number of Samples
Average Defect Percentage 40 µm <0.1 % -
Average Defect Percentage 80 µm <0.2 % -

Mechanical Properties

Mechanical Properties Heat Treated

EN ISO 6892-1 Room Temperature | 40 µm Yield Strength [MPa] Tensile Strength [MPa] Elongation at Break A [%] Reduction of Area Z [%] Modulus of elasticity [GPa] Number of Samples
Vertical 1240 1360 14 - - -
Horizontal 1240 1360 14 - - -

H900 Heat treatment

Mechanical Properties Heat Treated

EN ISO 6892-1 Room Temperature | 80 µm Yield Strength [MPa] Tensile Strength [MPa] Elongation at Break A [%] Reduction of Area Z [%] Modulus of elasticity [GPa] Number of Samples
Vertical 1240 1360 13 - - -
Horizontal 1230 1355 14 - - -

H900 Heat treatment

Impact Toughness

EN ISO 148-1, Charpy-V Heat Treated
Typical Impact Toughness [J] 20
Layer Thickness 40 µm

H900 Heat treatment

Heat Treated
Typical Impact Toughness [J] 20
Layer Thickness 80 µm

H900 Heat treatment

Surface Roughness

Coefficient of Thermal Expansion

ASTM E228 Temperature
10.4*10-6/K 25 – 100 ºC
11.1*10-6/K 25 – 200 ºC
11.4*10-6/K 25 – 300 ºC
11.8*10-6/K 25 – 400 ºC
Process Data Sheet

EOS StainlessSteel 17-4PH on EOS M 400-4 | 40/80 µm

EOS M 400-4 - 40 µm - TRL 3

Process Information Metal

This process product is optimized for flexible and fast production of 17-4PH parts with M 400-4 system. The parameter  set has three different layer thickness options that can all be utilized within the same build: 40µm, 80 µm and 40/80 µm Skin. For high productivity needs a 80 µm parameter set is included with a build rate more than double the long established 40 µm parameter set. Both can be used separately for different parts or combined by using 40/80 µm Skin with faster 80 µm for the core of the part and higher quality 40 µm building for the surface of the part with defined thickness. Sectionioning parts in vertical direction for different parameters is also possible.

System Setup EOS M 400-4
EOS Material set 17-4PH_040_080_Core M404
Required Software Plan EOS BUILD
Software Requirements

EOSPRINT 2.14 or newer
EOSYSTEM 2.18 or newer

Recoater Blade Ceramic
Inert gas Argon
Sieve 75 µm
Additional Information
Layer Thickness 40/80 µm
Volume Rate 4.1 -7.9 mm³/s
Typical Dimensional Change after HT [%] +0.2 %

Chemical and Physical Properties of Parts

Microstructure of the Produced Parts

Defects Thickness Result Number of Samples
Average Defect Percentage 40 µm <0.1 % -
Average Defect Percentage 80 µm <0.2 % -

Mechanical Properties

Mechanical Properties Heat Treated

EN ISO 6892-1 Room Temperature | 40 µm Yield Strength [MPa] Tensile Strength [MPa] Elongation at Break A [%] Reduction of Area Z [%] Modulus of elasticity [GPa] Number of Samples
Vertical 1245 1350 13 - - -
Horizontal 1240 1360 13 - - -

H900 Heat treatment

Mechanical Properties Heat Treated

EN ISO 6892-1 Room Temperature | 80 µm Yield Strength [MPa] Tensile Strength [MPa] Elongation at Break A [%] Reduction of Area Z [%] Modulus of elasticity [GPa] Number of Samples
Vertical 1190 1350 14 - - -
Horizontal 1180 1360 14 - - -

H900 Heat treatment

Impact Toughness

EN ISO 148-1, Charpy-V Heat Treated
Typical Impact Toughness [J] 20
Layer Thickness 40 µm

H900 Heat treatment

Heat Treated
Typical Impact Toughness [J] 20
Layer Thickness 80 µm

H900 Heat treatment

Surface Roughness

Coefficient of Thermal Expansion

ASTM E228 Temperature
10.4*10-6/K 25 – 100 ºC
11.1*10-6/K 25 – 200 ºC
11.4*10-6/K 25 – 300 ºC
11.8*10-6/K 25 – 400 ºC
Process Data Sheet

EOS StainlessSteel 17-4PH for EOS M 290 | 40 µm

EOS M 290 - 40 µm - TRL 7

Process Information Metal

This process product is optimized for flexible and reliable production of 17-4PH parts with emphasis on quality.

System Setup EOS M 290
EOS Material set 17-4PH_040_StainlessM291
Software Requirements

EOSPRINT 1.5 or newer
EOSYSTEM 2.5 or newer

Recoater Blade Ceramic
Nozzle EOS Grid Nozzle
Inert gas Argon
Sieve 75 µm
Additional Information
Layer Thickness 40 µm
Volume Rate 3.3 mm³/s
Typical Dimensional Change after HT [%] +0.2 %

Chemical and Physical Properties of Parts

Microstructure of the Produced Parts

Defects Thickness Result Number of Samples
Average Defect Percentage - 0.03 % -
Density EN ISO 3369 Thickness Result Number of Samples
Average Density - ≥7.79 g/cm³ -

Mechanical Properties Heat Treated

EN ISO 6892-1 Room Temperature Yield Strength [MPa] Tensile Strength [MPa] Elongation at Break A [%] Reduction of Area Z [%] Number of Samples
Vertical 1250 1340 13.5 - - -
Horizontal 1235 1335 14 - - -

H900 Heat treatment

Mechanical Properties As Manufactured

EN ISO 6892-1 Room Temperature Yield Strength [MPa] Tensile Strength [MPa] Elongation at Break A [%] Reduction of Area Z [%] Number of Samples
Vertical 860 920 20 - - -
Horizontal 890 860 20 - - -

Hardness

EN ISO 6508 Heat Treated
Value 42
Unit HRC
EN ISO 6508 As Manufactured
Value 24
Unit HRC

Surface Roughness

Coefficient of Thermal Expansion

ASTM E228 Temperature
10.4*10-6/K 25 – 100 ºC
11.1*10-6/K 25 – 200 ºC
11.4*10-6/K 25 – 300 ºC
11.8*10-6/K 25 – 400 ºC
Process Data Sheet

EOS StainlessSteel 17-4PH for EOS M 300-4 | 40 µm

EOS M 300-4 - 40 µm - TRL 3

System Setup EOS M 300-4
EOS Material set 17-4PH_040_CoreM304
Software Requirements

EOSPRINT 2.11 or newer
EOSYSTEM 2.15 or newer

Recoater Blade Ceramic
Build Platform Temperature 80 °C
Inert gas Argon
Sieve 75 µm
Additional Information
Layer Thickness 40 µm
Volume Rate up to 4 x 3.32 mm³/s

Microstructure of the Produced Parts

Defects Thickness Result Number of Samples
Average Defect Percentage - 0.014 % -

Mechanical Properties

Mechanical Properties As Manufactured

EN ISO 6892-1 Room Temperature | Yield Strength [MPa] Tensile Strength [MPa] Elongation at Break A [%] Reduction of Area Z [%] Modulus of elasticity [GPa] Number of Samples
Vertical 947 1052 15.7 - - -
Horizontal 941 1015 16.8 - - -

Mechanical Properties Heat Treated

EN ISO 6892-1 Room Temperature | Yield Strength [MPa] Tensile Strength [MPa] Elongation at Break A [%] Reduction of Area Z [%] Modulus of elasticity [GPa] Number of Samples
Vertical 1240 1371 10.5 - - -
Horizontal 1207 1349 10.7 - - -
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